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Atomic: M.A.C. | Reference
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Reactions of Magnesium
Reactions with water
Although magnesium does not react with water to any significant extent it does react with steam to yield magnesium oxide, or magnesium hydroxide with excess steam, and hydrogen gas.
  Mg(s) + H2O(g)MgO(aq) + H2(g)
  Mg(s) + excess 2H2O(g)Mg(OH)2(aq) + H2(g)
Reactions with air
A thin layer of oxide helps to protect magnesium from attack by air. However, once ignited magnesium burns in air with its characteristic intensely bright white flame. This yields magnesium oxide and magnesium trioxide.
  2Mg(s) + O2(g)2MgO(s)
  3Mg(s) + N2(g)Mg3N2(s)
Reactions with halogens
Magnesium will react with chlorine and bromine to form magnesium(II) dihalides.
  Mg(s) + Cl2(g)MgCl2(s)
  Mg(s) + Br2(g)MgBr2(s)
Reactions with acids
Magnesium will dissolve readily in dilute sulphuric acid, as will as other acids, to form solutions containing the Mg(II) ion and hydrogen gas.
  Mg(s) + H2SO4(aq)Mg2+(aq) + SO42-(aq) + H2(g)
  Mg(s) + 2HCl(aq)Mg2+(aq) + 2Cl-(aq) + H2(g)
Reactions with bases
Magnesium appears not to react with dilute alkalis.
 
Reduction Potentials
Balanced half-reaction E0 / V
Mg2+ + 2e-Mg(s) -2.363
Mg(OH)2(s) + 2e-Mg(s) + 2OH- -2.69
MgO(s) + 2H+ + 2e-Mg(s) + H2O -1.722